Organic Compounds containing Nitrogen

Preparation

 * 1) Vapour Phase Nitration
 * 2) From Alkyl Halides
 * 3) From Salts of α Halogeno Carboxylic Acids
 * 4) From α-Nitroalkenes
 * 5) From Oxime
 * 6) From 10 Amines

Reactions

 * 1) With Nitrous Acid (HNO2)
 * 2) Halogenation (Dihalo derivative)
 * 3) Condensation with Aldehydes and Ketones
 * 4) Hydrolysis
 * 5) Reduction to Amines
 * 6) Nef Carbonyl Synthesis

Preparation of 10 Amines

 * 1) Gabriel's phthalimide Synthesis
 * 2) Ammonolysis of Alkyl Halides
 * 3) Reduction
 * 4) * of Oxime
 * 5) * of Alkyl Cyanide
 * 6) * of Amides
 * 7) * of Nitro Compounds
 * 8) Hoffmann's Bromamide Degradation (from Amides)

Reactions

 * 1) Hoffmann's Carbylamine Test or Isocyanide test
 * 2) Hinsberg's Test (aryl sulphonyl chloride)
 * 3) Action of Nitrous Acid (HNO2)
 * 4) Hoffmann's Exhaustive Alkylation
 * 5) Acylation of Amines
 * 6) Hoffmann's Elimination

Physical Properties
The MP of Tertiary amines is lower due to absence of hydrogen to form intermolecular hydrogen bonding.

Preparation

 * 1) from Aniline

Reactions

 * 1) Halogenation by Sandmeyer Reaction (For Cl, Br , CN)
 * 2) Gattermann Reaction (For Cl, Br)
 * 3) For Halogenation using Iodine and Fluorine
 * 4) Formation of Nitrobenzene, Phenol and Benzene
 * 5) Azo Coupling